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Aliphatic fluoro diazo compounds Communication 2. Perfluoro(α-diazo ketones)

  • B. L. Dyatkin
  • E. P. Mochalina
Organic and Biological Chemistry

Summary

  1. 1.

    By the action of 2-diazo-1,1,1-trifluoroethane on perfluoro carboxylic anhydrides a number of perfluoro(α-diazo ketones) were obtained.

     
  2. 2.

    With the case of 3-diazohexafluoro-2-butanone as example, some chemical properties of perfluoro(α-diazo ketones) were investigated. The pyrolysis of 3-diazohexafluoro-2-butanone is accompanied by Wolff rearrangement and leads to bistrifluoromethylketene.

     

Keywords

Pyrolysis Ketone Anhydride Chemical Property Fluoro 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau Enterprises, Inc. 1966

Authors and Affiliations

  • B. L. Dyatkin
    • 1
  • E. P. Mochalina
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of SciencesUSSR

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