Summary
-
1.
We have measured the oxidation-reduction potentials and ultraviolet spectra of a series of isomeric disubstituted ferrocenes.
-
2.
In the case of amides of substituted ferrocene carboxylic acids, we found actual differences of the 1,2-isomers from the others,both in the ultraviolet spectra and the values of the oxidation-reduction potentials.
Similar content being viewed by others
Literature cited
G G. Dvoryantseva, Yu. N. Sheinker, L. P. Yur'eva, and A. N. Nesmeyanov, Dokl. AN SSSR,156, 873 (1964).
A. N. Nesmeyanov, É. G. Perevalova, L. P. Yur'eva, and L. N. Kakurina, Izv. AN SSSR, Ser. khim.,1964, 1897.
A. N. Nesmeyanov, É. G. Perevalova, and L. P. Yur'eva, Izv. AN SSSR, Ser. khim.,1965, 907.
S. P. Gubin and É. G. Perevalova, Dokl. AN SSSR,154, 1351 (1962).
É. G. Perevalova, S. P. Gubin, S. A. Smirnova, and A. N. Nesmeyanov, Dokl. AN SSSR,154, 126 (1964).
L. L. Ingraham, Effect of Spacial Factors on Some Physical Properties, in the book, Special Effects in Organic Chemistry, edited by Newman [Russian translation], IL, Moscow (1960), p. 489.
W. R. Remington, J. Amer. Chem. Soc.,67, 1838 (1945).
R. B. Turner and D. M. Voitle, J. Amer. Chem. Soc.,73, 1403 (1951).
K. L. Rinehart, K. L. Motz, and S. Moon, J. Amer. Chem. Soc.,79, 2749 (1957).
M. Rosenblum and R. B. Woodward, J. Amer. Chem. Soc.,80, 5443 (1958).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 907–909, May, 1965 Original article submitted July 29, 1964
We thank L. S. Shilovtseva for giving us the methylethyl- and ethylhydroxymethyl ferrocenes.
Rights and permissions
About this article
Cite this article
Nesmeyanov, A.N., Perevalova, É.G., Yur'eva, L.N. et al. The oxidation-reduction potential and absorption spectra in the ultraviolet and visible regions of some homoannular disubstituted ferrocenes. Russ Chem Bull 14, 878–880 (1965). https://doi.org/10.1007/BF00845710
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00845710