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Synthesis and reactions of tribromogermane

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    New methods are proposed for the preparation of HGeBr3, GeBr2, and GeI3.

  2. 2.

    In its chemical transformations,tribromogermane behaves like trichlorogermane, but it has a greater tendency to undergo condensation than addition.

  3. 3.

    Germanium dibromide reacts with allyl bromide and with butadiene with formation of allyltribromogermane and 1,1-dibromo-3,4-dihydro-1H-germole respectively.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    T. K. Gar & V. F. Mironov

Authors
  1. T. K. Gar
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  2. V. F. Mironov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 855–862, May, 1965 Original article submitted September 3, 1964

This article is published in accordance with a resolution of the Conference of Chief Editors of Journals of the Academy of Sciences of the USSR of July 12, 1962, as a dissertation paper by T. K. Gar.

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Gar, T.K., Mironov, V.F. Synthesis and reactions of tribromogermane. Russ Chem Bull 14, 827–833 (1965). https://doi.org/10.1007/BF00845697

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  • DOI: https://doi.org/10.1007/BF00845697

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