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Isomerization of 2,3-epoxypinane and 3,4-epoxycarane by lithium diethylamide

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

A study was made of the isomerization of 2,3-epoxypinane and 3,4-epoxycarane by means of lithium diethylamide. 2,3-Epoxypinane is isomerized into trans-2(10)-pinen-3-ol, whereas 3,4-epoxycarane forms a mixture of alcohols: 3(10)-caren-4-ol, p-mentha-1,5-dien-8-ol, and m-mentha-4,6-dien-2-ol.

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Authors and Affiliations

  1. V. I. Ul'yanov-Lenin Kazan' State University, USSR

    B. A. Arbuzov, Z. G. Isaeva & I. S. Andreeva

Authors
  1. B. A. Arbuzov
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  2. Z. G. Isaeva
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  3. I. S. Andreeva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 838–843, May, 1965 Original article submitted April 22, 1963

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Arbuzov, B.A., Isaeva, Z.G. & Andreeva, I.S. Isomerization of 2,3-epoxypinane and 3,4-epoxycarane by lithium diethylamide. Russ Chem Bull 14, 813–816 (1965). https://doi.org/10.1007/BF00845693

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  • DOI: https://doi.org/10.1007/BF00845693

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