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Catalytic conversions of high-molecular paraffins Communication 3. Influence of the addition of benzene in the isomerization of n-octadecane in the presence of the industrial catalyst WS2

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The influence of benzene on the isomerization of n-octadecane in the presence of a freshly sulfurized catalyst WS2 was studied at a temperature of 400° and presence of 20 atm.

  2. 2.

    The addition of 6% benzene causes a certain inhibition of cracking of the isooctadecanes formed and increases the total selectivity of the isomerization reaction.

  3. 3.

    Speculations on the mechanism of the isomerization and the action of additions of benzene on the catalyst studied were expressed.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences, Kazan', USSR

    Kh. Ya. Orlov & A. A. Martynov

Authors
  1. Kh. Ya. Orlov
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  2. A. A. Martynov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 796–800, May, 1965

The authors would like to express their deep gratitude to S. K. Ermakova for carrying out the Chromatographic analyses.

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Orlov, K.Y., Martynov, A.A. Catalytic conversions of high-molecular paraffins Communication 3. Influence of the addition of benzene in the isomerization of n-octadecane in the presence of the industrial catalyst WS2 . Russ Chem Bull 14, 778–781 (1965). https://doi.org/10.1007/BF00845686

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  • DOI: https://doi.org/10.1007/BF00845686

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