Synthesis and properties of silicon- and germanium-containing hydrocarbons of the cyclopropane series

  • I. E. Dolgii
  • A. P. Meshcheryakov
  • G. K. Gaivoronskaya
Organic and Biological Chemistry
  • 30 Downloads

Summary

  1. 1.

    Hydrocarbons of the cyclopropane series containing silicon and germanium have been obtained for the first time and their properties described.

     
  2. 2.

    In the reaction of the unsaturated silicon-hydrocarbons studied with methylene iodide in the presence of a zinc-copper couple, neither theα-orβ-position of the double bond relative to silicon (in the cases of the trimethyl and trimethylvinyl-silane) nor the nature of the element in theβ-position to the double bond (in the cases of trimethylallylsilane, trimethylallylgermane, and 4,4-dimethylpentene-1) showed a marked effect on the yield of the cyclopropane derivatives.

     

Keywords

Methylene Silicon Hydrocarbon Iodide Double Bond 

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Literature cited

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Copyright information

© Consultants Bureau Enterprises, Inc. 1964

Authors and Affiliations

  • I. E. Dolgii
    • 1
  • A. P. Meshcheryakov
    • 1
  • G. K. Gaivoronskaya
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryUSSR Academy of SciencesUSSR

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