Synthesis and properties of silicon- and germanium-containing hydrocarbons of the cyclopropane series
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Hydrocarbons of the cyclopropane series containing silicon and germanium have been obtained for the first time and their properties described.
In the reaction of the unsaturated silicon-hydrocarbons studied with methylene iodide in the presence of a zinc-copper couple, neither theα-orβ-position of the double bond relative to silicon (in the cases of the trimethyl and trimethylvinyl-silane) nor the nature of the element in theβ-position to the double bond (in the cases of trimethylallylsilane, trimethylallylgermane, and 4,4-dimethylpentene-1) showed a marked effect on the yield of the cyclopropane derivatives.
KeywordsMethylene Silicon Hydrocarbon Iodide Double Bond
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