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Synthesis and isomerization of 2-n-propyl-5-phenyltetrahydrofuran

  • N. I. Shuikin
  • I. Ap'ok
  • M. Bartok
  • I. F. Bel'skii
  • R. A. Karakhanov
Brief Communications
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Summary

  1. 1.

    The synthesis of 2-n-propyl-5-phenyltetrahydrofuran was accomplished by catalytic hydrogenation of 1-furyl-3-phenylpropanol-3 in the vapor phase on Pt-C at 220°.

     
  2. 2.

    2-n-Propyl-5-phenyltetrahydrofuran is isomerized on Pt-C at 300° with opening of the ring at bothC-O bonds: 48% at the bond next to the phenyl radical, and 10% at the bond next to the propyl radical.

     

Keywords

Hydrogenation Phenyl Vapor Phase Propyl Phenyl Radical 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    I. F. Bel'skii and N. I. Shuikin, Dokl. AN SSSR128, 945 (1949).Google Scholar
  2. 2.
    N. I. Shuikin and I. F. Bel'skii, Dokl. AN SSSR137, 622 (1961).Google Scholar
  3. 3.
    I. F. Bel'skii and N. I. Shuikin, Izv. AN SSSR, Otd. Khim. N.1962, 1656.Google Scholar
  4. 4.
    N. I. Shuikin and I. F. Bel'skii, Dokl. AN SSSR120, 548 (1958).Google Scholar
  5. 5.
    N. I. Shuikin, I. F. Bel'skii, and R. A. Karakhanov, Dokl. AN SSSR127, 815 (1959).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1965

Authors and Affiliations

  • N. I. Shuikin
    • 1
  • I. Ap'ok
    • 1
  • M. Bartok
    • 1
  • I. F. Bel'skii
    • 1
  • R. A. Karakhanov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of SciencesUSSR

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