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Reaction of ethylene oxide with methyl isothiocyanate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

When ethylene oxide reacts with methyl isothiocyanate in the presence of tetraethylammonium bromide, basically a compound of the spiran type (I) is obtained; thermal decomposition of this compound results in the formation of the trimethyl ester of dithioisocyanuric acid and ethylene sulfide.

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Literature cited

  1. K. A. Krasuskii and M. Movsum-Zade, Zh. Obshch. Khimii6, 1203 (1936).

    Google Scholar 

  2. J. I. Jones and H. G. Savill, J. Chem. Soc.1957, 4392.

  3. J. Burkus, J. Organ. Chem.27, 474 (1962).

    Google Scholar 

  4. K. Gulbins and K. Hamann, Angew. Chem.70, 705 (1958).

    Google Scholar 

  5. K. Gulbins, G. Benzing, R. Maysenhölder, and K. Hamann, Chem. Ber.93, 1975 (1960).

    Google Scholar 

  6. U. S. Patent 2977.369 (1961); RZhKhim, 9L153 (1962).

  7. G. P. Speranza and W. J. Peppel, J. Organ. Chem.23, 1922 (1958).

    Google Scholar 

  8. M. L. Weiner, J. Organ. Chem.26, 951 (1961).

    Google Scholar 

  9. Beilstein,26, 249.

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Authors
  1. V. S. Étlis
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  2. A. P. Sineokov
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  3. G. A. Razuvaev
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Étlis, V.S., Sineokov, A.P. & Razuvaev, G.A. Reaction of ethylene oxide with methyl isothiocyanate. Russ Chem Bull 13, 682–683 (1964). https://doi.org/10.1007/BF00845320

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  • DOI: https://doi.org/10.1007/BF00845320

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