Summary
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1.
The interaction of symtetracyanobenzene with naphthalene, anthracene, and naphthacene at 250–300° leads to products containing a substantial number of paramagnetic particles and possessing electric conductivity at 25° up to 10−3.3ω−1·cm−1, with an activation energy of 0.15–0.20 eV.
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2.
in the cases described, the effect of local activation is manifested, i.e., the appearance of paramagnetic particles in the local magnetic fields of the preexisting particles, and polymerization and copolymerization products are formed.
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Literature cited
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The authors are grateful to N. Ya. Buben, to whom they are indebted for an investigation of the temperature dependence of the EPR spectra.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya No. 11, pp. 2108–2110, November, 1964
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Berlin, A.A., Parini, V.P., Frankevich, E.L. et al. On the effect of local activation in the interaction of tetracyanobenzene with some aromatic hydrocarbons. Russ Chem Bull 13, 2012–2014 (1964). https://doi.org/10.1007/BF00844511
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DOI: https://doi.org/10.1007/BF00844511