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Alkylation of toluene with alkyl halides and ratio of the isomers formed

  • S. V. Vitt
  • N. A. Zharikova
  • E. A. Paskonova
  • V. B. Bondarev
Brief Communications
  • 26 Downloads

Summary

  1. 1.

    The alkylation of toluene with alkyl halides was studied under conditions of brief contact at 0° in the presence of AlCl3.

     
  2. 2.

    The Chromatographic separation of isomeric dialkylbenzenes was studied on a capillary steel column with apiezon-L and polypropylene glycol.

     
  3. 3.

    The relative content of the o-isomer, formed in the process of replacement, is determined by steric factors.

     

Keywords

Toluene Glycol Polypropylene Alkylation Halide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    R. H. Allen, J. D. Jats, and D. S. Erley, J. Am. Chem. Soc.,82, 4853 (1960).Google Scholar
  2. 2.
    H. C. Brown and H. Jungh, J. Am. Chem. Soc.,77, 5579 (1955).Google Scholar
  3. 3.
    W H. Kutz, J. E. Nickels, J. J. McCovern, and B. B. Corson, J. Organ. Chem.,16, 699 (1951).Google Scholar
  4. 4.
    W. J. Taylor, D. D. Wagman, H. G. Williams, C. S. Pitz, and F. D. Rossini, J. Res. Nat. Bur. Standards,37, 95 (1946).Google Scholar
  5. 5.
    R. H. Allen and L. D. Iats, J Am. Chem. Soc.,81, 5289 (1959).Google Scholar
  6. 6.
    R. H. Allen, J. Am. Chem. Soc.,82, 4856 (1960).Google Scholar
  7. 7.
    R. H. Allen, Alfrey, and L. D. Jats, J. Am. Chem. Soc.,81, 42 (1959).Google Scholar
  8. 8.
    I. M. Kolesnikov and G. M. Panchenkov, Neftekhimiya, No. 1, 48 (1962).Google Scholar

Copyright information

© Consultants Bureau 1965

Authors and Affiliations

  • S. V. Vitt
    • 1
    • 2
  • N. A. Zharikova
    • 1
    • 2
  • E. A. Paskonova
    • 1
    • 2
  • V. B. Bondarev
    • 1
    • 2
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR
  2. 2.Institute of Biochemistry and Physiology of MicroorganismsAcademy of Sciences of the USSRUSSR

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