Summary
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1.
The alkylation of toluene with alkyl halides was studied under conditions of brief contact at 0° in the presence of AlCl3.
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2.
The Chromatographic separation of isomeric dialkylbenzenes was studied on a capillary steel column with apiezon-L and polypropylene glycol.
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3.
The relative content of the o-isomer, formed in the process of replacement, is determined by steric factors.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya No. 11, pp. 2099–2101, November, 1964
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Vitt, S.V., Zharikova, N.A., Paskonova, E.A. et al. Alkylation of toluene with alkyl halides and ratio of the isomers formed. Russ Chem Bull 13, 2002–2004 (1964). https://doi.org/10.1007/BF00844507
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DOI: https://doi.org/10.1007/BF00844507