Summary
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1.
The barene ring of phenylbarene and its derivatives is oxidized by hydrogen peroxide in the presence of alkalis.
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2.
A two-step method has been proposed for the oxidation of phenylbarene and its derivatives to the corresponding benzoic acids.
Literature cited
L. I. Zakharkin, V. I. Stanko, V. A. Brattsev, Yu. A. Chapovskii, and O. Yu. Okhlobystin, Izd. AN SSSR, ScI. Khim.,1963, 2238.
L. I. Zakharkin, V. I. Stanko, V. A. Brattsev, Yu. A. Chapovskii, A. I. Klimova, O. Yu. Okhlobystin, and A. A. Ponomarenko, DAN SSSR (1964).
Morton, Le Fevre, and Hechenbleikner, J. Am. Chem. Soc.,58, 754 (1963).
A. M. Berkengeis and S. I. Lur'e, Zh. Obshch. Khimii,6, 1043 (1936).
Conn and Lowy, Chem. Zbl.,1937, 11, 2789.
Preparative Organic Chemistry [in Russian] (GoskhimIzdat, Moscow, 1959), p. 678.
Asinger and Lock, Monatsh. Chem.,62, 344 (1933).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya No. 11, pp. 2091–2093, November, 1964
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Zakharkin, L.I., Stanko, V.I. & Brattsev, V.A. Method of oxidation of phenylbarene and its derivatives. Russ Chem Bull 13, 1992–1994 (1964). https://doi.org/10.1007/BF00844503
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DOI: https://doi.org/10.1007/BF00844503