Summary
-
1.
The EPR spectrum of the radicals formed in the reaction of hydrogen atoms with acetylene in the gas phase at temperatures 20 and 280° and frozen by liquid nitrogen was studied; in addition, the EPR spectrum of the radicals obtained under the action of H atoms on acetylene frozen at a temperature of −196° was studied.
-
2.
The main reaction product at low temperatures, all the way up to 20°, was the radical C2H3; when the temperature is raised, still another radical, most likely C2H, is formed in appreciable amounts.
This is a preview of subscription content, log in via an institution to check access.
Literature cited
L. I. Avramenko, R. V. Kolesnikova, and G. I. Savinova, Izd. AN SSSR, Ser. khim. (in press).
L. I. Avramenko, N. Ya. Buben, R. V. Kolesnikova, V. A. Tolkachev, and I. I. Chkheidze, Izd. AN SSSR, Otd. khim. n.,1962, 2079.
E. L. Cochran, V. A. Bowers, and F. J. Adrian, Sixth intern. Symp. on Free Radicals, University of Cambridge, July, 1963.
D. I. Shigorin et al., DAN SSSR,140, 419 (1961).
Author information
Authors and Affiliations
Additional information
The authors would like to thank I. I. Chkheidze for his discussion of the results.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya No. 11, pp. 2090–2091, November, 1964
Rights and permissions
About this article
Cite this article
Buben, N.Y., Kolesnikova, R.V., Kuznetsova, N.L. et al. Radicals formed in the reaction of atomic hydrogen with C2H4 . Russ Chem Bull 13, 1990–1991 (1964). https://doi.org/10.1007/BF00844502
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00844502