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Gas — Liquid chromatography of some unsaturated organosilicon compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The retention times of the following vinyl- and allylderivatives of silicon: (CH3)3 3SiCH = CH2, (C2H5)3SiCH=CH2, (C3H7)3SiCH = CH2, (CH3)2C6H5SiCH =CH2, (CH3)3SiCH2-CH= CH2, (CH3)2Si(CH3-CH = CH2)2, CH3Si(CH2-CH= CH2)3, Si(CH2-CH=CH2)4, (CH2= CH-CH2)3SiH were determined on two stationary liquid phases of different polarity (methylphenylpolysiloxane oil PFMS-4 and polyethylene glycol, with molecular weight 1500).

  2. 2.

    The logarithm of the relative retention time of unsaturated silicohydrocarbons can be represented as the sum of the partial values corresponding to definite combinations of bonds.

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Literature cited

  1. A. V. Topchiev, N. S. Nametkin, Ch'iu Hsiao-p'ei, S. G. Durgar'yan, and V. I. Zav'yalov, Izd. AN SSSR, Old. khim. n.,1963, 229.

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Authors and Affiliations

  1. A. V. Topchiev institute of Petrochemical Synthesis, Academy of Sciences of the USSR, USSR

    N. S. Nametkin, N. Ya. Shuinova & V. G. Berezkin

Authors
  1. N. S. Nametkin
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  2. N. Ya. Shuinova
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  3. V. G. Berezkin
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Additional information

The authors would like to express their profound gratitude to S. G. Durgar'yan for his discussion of the work and for providing the necessary compounds.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya No. 11, pp. 2080–2082, November, 1964

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Nametkin, N.S., Shuinova, N.Y. & Berezkin, V.G. Gas — Liquid chromatography of some unsaturated organosilicon compounds. Russ Chem Bull 13, 1977–1979 (1964). https://doi.org/10.1007/BF00844497

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  • DOI: https://doi.org/10.1007/BF00844497

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