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Study of the kinetics of the thermal decomposition of chlorine-containing carbon-chain polymers

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The influence of the structure of a chlorine-containing polymer on the kinetics of its thermal decomposition was demonstrated.

  2. 2.

    The polymers can be arranged in the following series with respect to increasing relative rate and decreasing activation energy of the decomposition process: polyvinyl chloride, chlorinated polyvinyl chloride, polyvinylidene chloride, copolymer of vinyl chloride with vinylidene chloride (activation energies equal to 33.5, 31.6, 28.7, and 27.5 kcal/mole, respectively).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    A. A. Berlin, R. M. Aseeva, Z. S. Smutkina & V. I. Kasatochkin

Authors
  1. A. A. Berlin
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  2. R. M. Aseeva
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  3. Z. S. Smutkina
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  4. V. I. Kasatochkin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya No. 11, pp. 1974–1979, November, 1964

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Berlin, A.A., Aseeva, R.M., Smutkina, Z.S. et al. Study of the kinetics of the thermal decomposition of chlorine-containing carbon-chain polymers. Russ Chem Bull 13, 1879–1883 (1964). https://doi.org/10.1007/BF00844480

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  • DOI: https://doi.org/10.1007/BF00844480

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