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Investigation of the kinetics and mechanism of the hydrolysis of dichlorides of carboxylic a-cids

3. Hydrolysis of acid chlorides in the presence of acids and alkalis

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The hydrolysis of phthalyl and terephthalyl chlorides was investigated in dioxane in the presence of additions of HC1, KOH, and carboxylic acids.

  2. 2.

    Hydrochloric acid does not influence the rate of hydrolysis of acid chlorides, while additions of terephthalic acid accelerate the hydrolysis of terephthalyl chloride.

  3. 3.

    The rate of hydrolysis of acid chlorides drops at low concentrations of the alkali added to the reaction medium, but then begins to rise sharply.

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Literature cited

  1. S. G. Éntelis, R. P. Tiger, É. Ya. Nevel'skii, and I. V. Épel'baum, Izv. AN SSSR, Otd. khim. n.,1963, 245.

  2. S. G. Éntelis, R. P. Tiger, É. Ya. Nevel'skii, and I. V. Épel'baum, Izv. AN SSSR, Otd. khim. n.,1963, 429.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    R. P. Tiger, É. Ya. Nevel'skii, I. V. Épel'baum & S. G. Éntelis

Authors
  1. R. P. Tiger
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  2. É. Ya. Nevel'skii
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  3. I. V. Épel'baum
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  4. S. G. Éntelis
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya No. 11, pp. 1969–1974, November, 1964

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Tiger, R.P., Nevel'skii, É.Y., Épel'baum, I.V. et al. Investigation of the kinetics and mechanism of the hydrolysis of dichlorides of carboxylic a-cids. Russ Chem Bull 13, 1875–1878 (1964). https://doi.org/10.1007/BF00844479

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  • DOI: https://doi.org/10.1007/BF00844479

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