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Structure and polarographic behavior of certain iodomethyltrialkyl(aryl)silanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The observed doubling of the two-electron polarographic reduction waves of iodomethyltrialkyl(aryl)silanes into two one-electron waves is due to the formation of comparatively stable radicals: intermediate products of the reduction process.

  2. 2.

    It was shown for the example of iodomethyltriethylsilane that the individual steps move apart along the potential axis as the dropping period and temperature increase.

  3. 3.

    The values of the half-wave potentials of both stages of the reduction of the indicated iodides are correlated for most compounds with the values of the polar constants of the silyl groups.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    S. G. Mairanovskii, V. A. Ponomarenko, N. V. Barashkova & M. A. Kadina

Authors
  1. S. G. Mairanovskii
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  2. V. A. Ponomarenko
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  3. N. V. Barashkova
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  4. M. A. Kadina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya No. 11, pp. 1951–1956, November, 1964

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Mairanovskii, S.G., Ponomarenko, V.A., Barashkova, N.V. et al. Structure and polarographic behavior of certain iodomethyltrialkyl(aryl)silanes. Russ Chem Bull 13, 1858–1862 (1964). https://doi.org/10.1007/BF00844476

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  • DOI: https://doi.org/10.1007/BF00844476

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