Summary
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1.
Organic compounds of silicon and germanium containing a three-membered carbon ring in the molecule have been prepared for the first time.
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2.
Silicon and germanium atoms, when these heteroatoms are in the β-position to the C=C bond, on the yields of the esters of the corresponding cyclopropanecarboxylic acids, which were prepared by the reaction of uasaturated compounds of these elements with diazoacetic ester in the presence of a catalyst.
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Literature cited
I. A. D'yakonov and V. F. Myznikova, Coll. Zh. obshch. khimii. 1. 483 (1953).
Yu. P. Egorov, L. A. Leites, and V. F. Mironov, Zh. strukturn. khimn. 2, No. 5, 562 (1961).
Yu. P. Egorov and P. A. Bazhulin, Dokl. AN SSSR,138, No. 4. 647 (1953).
A. P. Meshcheryakov and I. E. Dolgii. Izv. AN SSSR, Otd. khim. n. (1960), 1874.
A. D. Petrov, V. F. Mironov. V. A. Ponomarenko, and E. A. Chemyshev, Synthesis of organosilicon monomers [in Russian], Izd. AN SSSR (1961).
A. D. Petrov. V. F. Mironov. and I. E. Dolgii. Izv. AN SSSR, Otd. khim. n. (1956), 1146.
C. E. Boord, A. L. Henne, K. W. Greenlee, W. L. Perilstein, and J. M. Derfer, Industr. and Engng. Chem.,41, 609 (1949).
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Dolgii, I.E., Meshcheryakov, A.P. & Gaivoronskaya, G.K. Reaction of diazoacetic ester with unsaturated compounds of silicon and germanium. Russ Chem Bull 12, 519–521 (1963). https://doi.org/10.1007/BF00844422
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DOI: https://doi.org/10.1007/BF00844422