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The reaction of β- and γ- oxides with chlorides of phosphorus

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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Summary

  1. 1.

    When α-methyltrimethylene oxide, tetrahydrofuran, and tetrahydrosilvan react with phosphorus trichloride, chloroalkyl esters of phosphorous acid are formed in 50–55% yields.

  2. 2.

    The reaction of tetrahydrofuran with PCl5 apparently proceeds by a type of exchange reaction with opening of the ring at both C-O bonds and formation of 1,4-dichlorobutane and phosphorus oxychloride.

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Authors and Affiliations

  1. N. D. Zelinskii institute of Organic Chemistry, Academy of Sciences, USSR

    N. I. Shuikin, I. F. Bel'skii & I. E. Grushko

Authors
  1. N. I. Shuikin
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  2. I. F. Bel'skii
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  3. I. E. Grushko
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Shuikin, N.I., Bel'skii, I.F. & Grushko, I.E. The reaction of β- and γ- oxides with chlorides of phosphorus. Russ Chem Bull 12, 498–499 (1963). https://doi.org/10.1007/BF00844413

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  • DOI: https://doi.org/10.1007/BF00844413

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