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Formation of cycloheptatriene from benzene, carbon monoxide, and hydrogen over a cobalt catalyst

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    At 190° and 1–20 atm in presence of a Co-ThO2-kieselguhr catalyst (100∶18∶100) benzene in admixture with carbon monoxide and hydrogen forms small amounts of cycloheptatriene.

  2. 2.

    Under these conditions cycloheptatriene undergoes reaction to an almost quantitative extent.

  3. 3.

    The cycloheptatriene is probably formed by the reaction of benzene with methylene radicals formed by the incomplete reduction of carbon monoxide with hydrogen.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    Ya. T. Éidus, B. K. Nefedov & M. E. Vol'pin

  2. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    Ya. T. Éidus, B. K. Nefedov & M. E. Vol'pin

Authors
  1. Ya. T. Éidus
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  2. B. K. Nefedov
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  3. M. E. Vol'pin
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Éidus, Y.T., Nefedov, B.K. & Vol'pin, M.E. Formation of cycloheptatriene from benzene, carbon monoxide, and hydrogen over a cobalt catalyst. Russ Chem Bull 12, 490–492 (1963). https://doi.org/10.1007/BF00844410

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  • DOI: https://doi.org/10.1007/BF00844410

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