Summary
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1.
A study was made of the polymerization of some vinyl ethers of ethanolamines in presence of ionogenic and free-radical catalysts.
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2.
Vinyl ethers of ethanolamines are less reactive in ionic polymerization than unsubstituted alkyl vinyl ethers, and they tend to undergo radical polymerization under the initiation of azodiisobutyronitrile.
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3.
The relation of the structure of the ethanolamine vinyl ether to its tendency to polymerize was examined.
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4.
The introduction of an amide grouping into the β-position of the alkoxy group of an alkyl vinyl ether considerably increasedits reactivity in radical polymerization.
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5.
From vinyl ethers of ethanolamines polymers containing amino groups were prepared: both three -dimensional polymers, and linear polymers, some of which were water-soluble.
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Literature cited
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Chekulaeva, I.A., Lipovich, I.V. & Shostakovskii, M.F. Synthesis and transformations of vinyl ethers of ethanolamines. Russ Chem Bull 12, 479–482 (1963). https://doi.org/10.1007/BF00844408
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DOI: https://doi.org/10.1007/BF00844408