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Organoboron compounds

Communication 113. Reduction of trialkyl thioborates to bisalkylthioboranes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    In the reduction of trialkyl thioborates with lithium aluminum hydride, bisalkylthioboranes arc obtained.

  2. 2.

    Trimethyl thioborate forms a complex with lithium hydride — lithium hydrotrismethylthioborane. When treated with an equimolecular amount of hydrogen chloride, this is converted into bismethylthioborane.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    T. A. Shchegoleva, E. M. Shashkova & B. M. Mikhailov

Authors
  1. T. A. Shchegoleva
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  2. E. M. Shashkova
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  3. B. M. Mikhailov
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Additional information

For Commumcation 111 med 112 see [I].

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Shchegoleva, T.A., Shashkova, E.M. & Mikhailov, B.M. Organoboron compounds. Russ Chem Bull 12, 443–445 (1963). https://doi.org/10.1007/BF00844397

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  • DOI: https://doi.org/10.1007/BF00844397

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