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Kinetic determination of the energies of the bonds between the reacting atoms of organic molecules and the surface of blue molybdenum oxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A kinetic method has been used to find the energies of the bonds between organogens and the surface of MoO3-x. They have turned out to be close to the bond energies already found in MoO2 and MoS2, indicating that the bond energies are those for the bond between the organogen and the metal in the oxide.

  2. 2.

    For all the reactions studied, a logarithmic relation is satisfied between the constants in the Arrhenius equation.

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Literature cited

  1. A. A. Balandin, A. A. Tolsropyatova, and V. A. Naumov, Izv. AN SSSR, Otd. khim. n. (1962), 1150.

  2. A. A. Balandin and I. D. Rozhdestvenskaya, Izv. AN SSSR. Otd. khim. n. (1959), 1889.

  3. A. A. Balandin and A. A. Tolstopyatova, Problems in Kinetics and Catalysis, X., Physics and Physical Chemistry of Catalysis [in Russian], Moscow (1560).

  4. I. R. Konenko, Diploma work,MGU (1954).

  5. A. A. Balandin, A. A. Tolstopyatova. and V. Stshizhevskii, Dokl. AN SSSR134 625 (1960).

    Google Scholar 

  6. O. Glemser and G. Lutz, Z. anorgan. allgem. Chem.263 2 (1950).

    Google Scholar 

  7. O. Glemser and G. Lutz, Kolloid-z.119 99 (1950).

    Google Scholar 

  8. G. D. Gal'pern, Trudy instituta nefti4 141 (1954).

    Google Scholar 

  9. A. A. Tolstopyatova and A. A. Balandin, Zh. fiz. khimii.32 1831 (1958).

    Google Scholar 

  10. A. A. Tolstopyatova, K. A. Dulitskaya, and A. A. Balandin, Izv. AN SSSR Otd. khim. n. (1956).

  11. A. A. Balandin and I. I. Brusov, Zh. obshch. khimii.7 18 (1987).

    Google Scholar 

  12. A. A. Balandin, V. A. Ferapontov, and A. A. Tolstopyatova, tzv. AN SSSR, Otd. khim. n. (1960), 1751.

  13. V. N. Kondrat'ev, Uspekhi. khimii.26 861 (1957).

    Google Scholar 

  14. V. A. Naumov, Diploma work, MGU (1960).

  15. A. A. Balandin and A. A. Tolstopyatova, 2h. fiz. khimii.30 1367, 1636 (1956).

    Google Scholar 

  16. A. A. Tolstopyatova, A. A. Balandin, V. Kh. Matyushenko, and yu. I. Petrov, Izv. AN SSSR, Otd. khim. n. (1961), 583.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    A. A. Tolstopyatova, A. A. Balandin & V. A. Naumov

Authors
  1. A. A. Tolstopyatova
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  2. A. A. Balandin
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  3. V. A. Naumov
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Tolstopyatova, A.A., Balandin, A.A. & Naumov, V.A. Kinetic determination of the energies of the bonds between the reacting atoms of organic molecules and the surface of blue molybdenum oxide. Russ Chem Bull 12, 381–385 (1963). https://doi.org/10.1007/BF00844386

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  • DOI: https://doi.org/10.1007/BF00844386

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