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Radical reactions of alkyl nitrites with 2,4,6-trisubstituted phenols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    2,4,6-Trisubstituted phenols react with alkyl nitrites by a radical mechanism.

  2. 2.

    The direction of the reaction depends on the stability of the phenoxyl radicals which are formed as intermediates.

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Literature cited

  1. Ch. Walling, Free Radicals in Solution [Russian translation], IL, 1960, p. 416.

  2. V. V. Ershov and G. A. Zlobina, Izv. AN SSSR, Ser, Khim., 1963, 1667.

  3. G. A. Zlobina and V. V. Ershov, Izv. AN SSSR, Ser. Khim., 1964, 371.

  4. V. V. Ershov and G. A. Zlobina, Izv. AN SSSR, Ser. Khim., 1964, 2086.

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  9. G. A. Nikiforov, K. M. Dyumaev, A. A. Volod'kin, and V. V. Ershov, Izv. AN SSSR, Otd. Khim. N., 1962, 1836.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences, USSR

    V. V. Ershov & G. A. Zlobina

Authors
  1. V. V. Ershov
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  2. G. A. Zlobina
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Additional information

The authors thank N. M. émanuel' for constant interest in carrying out this work and A. L. Vuchachenko for taking the EPR spectra.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12 p. 2235–2237, December, 1964

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Ershov, V.V., Zlobina, G.A. Radical reactions of alkyl nitrites with 2,4,6-trisubstituted phenols. Russ Chem Bull 13, 2138–2140 (1964). https://doi.org/10.1007/BF00844240

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  • DOI: https://doi.org/10.1007/BF00844240

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