Summary
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1.
By heating N-triphenyl borazine we obtained and characterized a polyborazolylene.
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2.
B-Methyl-N-triphenyl borazine evolves practically no hydrogen when heated to 420‡ and undergoes disproportionation to only a slight degree at this temperature.
Literature cited
R. G. Wagner and I. L. Bradford, Inorgan. Chem.,1, No. 1, 99 (1962).
G. H. Smalley and S. F. Stafily, J. Amer. Chem. Soc.,81, 582 (1959).
U.S. Patent 2998449, 8/29/61, RZhKhim., 17L17 (1962).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12 p. 2223–2224, December, 1964
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Korshak, V.V., Zamyatina, V.A., Bekasova, N.I. et al. Polycondensation of N-triphenyl borazine. Russ Chem Bull 13, 2123–2124 (1964). https://doi.org/10.1007/BF00844234
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DOI: https://doi.org/10.1007/BF00844234