Summary
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1.
The diene condensations of dimethyl 2-propene-1-boronate with cyclopentadiene, hexachlorocyclopenta diene, and 1,2,3,4-tetrachlorocyclopentadiene, and also of dibutyl etheneboronate with hexachlorocyclopentadiene, were carried out.
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2.
The realtive activities of some dienophiles toward hexachlorocyclopentadiene were investigated. 2-Propene-1-and ethene-boronic esters condense more readily with hexachlorocyclopentadiene than other dienophiles do.
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The infrared spectra of the compounds were measured by E. Lubuzh, whom the authors thank.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12 p. 2170–2175, December, 1964
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Mikhailov, B.M., Bubnov, Y.N. Organoboron compounds, communication 133.. Russ Chem Bull 13, 2070–2073 (1964). https://doi.org/10.1007/BF00844217
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DOI: https://doi.org/10.1007/BF00844217