Summary
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1.
By the action of dimethylamine on boron trichloride and on boron tribromide, dichlorobis(dimethylamine)-boronium chloride and dibromobis(dimethylamine)boronium bromide were obtained, respectively.
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2.
The same salts were obtained by the reaction of dihalo(dimethylamino)boranes with dimethylamine salts.
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3.
By the action of pyridine hydrochloride on dichloro(dimethylamino)borane, and also by reaction between boron trichloride, pyridine, and dimethylamine, dichloro(dimethylamine)pyridineboronium chloride was synthesized.
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4.
By the treatment of ethereal and tetrahydrofuran solutions of boron trichloride with ferric chloride or stannic chloride the following substances were obtained: dichlorobis[diethyl ether]boronium and dichlorobis(tetrahydrofuran) boronium tetrachloroferrates(III) and dichlorobis(tetrahydrofuran)boronium hexachlorostannate(IV).
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Literature cited
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For communications 120–131 see [1].
For preliminary communication see [2].
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12 p. 2165–2170, December, 1964
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Mikhailov, B.M., Shchegoleva, T.A. & Sheludyakov, V.D. Organoboron compounds, communication 132. Synthesis of cationic complexes from boron trihalides. Russ Chem Bull 13, 2065–2069 (1964). https://doi.org/10.1007/BF00844216
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DOI: https://doi.org/10.1007/BF00844216