Advertisement

Microcoulometric investigation of the reduction of tropone, 2, 7 -dimethylbenztropone, and azulene at a dropping mercury cathode

  • A. A. Pozdeeva
  • S. I. Zhdanov
Physical Chemistry
  • 16 Downloads

Conclusions

It was established by a microcoulometric method that protonated tropone, 2,7-dimethylbenztropone, and azulene undergo a one-electron reduction in acid media on a dropping mercury electrode, forming radicals.

Keywords

Mercury Acid Medium Azulene Mercury Electrode Drop Mercury Electrode 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    J. Bartek, T. Mukai, T. Nozol, and F. Santavy, Collection19, 885 (1954).Google Scholar
  2. 2.
    B. Jambor, J. Bartek, and F. Santavy, Collection20, 1244 (1955).Google Scholar
  3. 3.
    S. I. Zhdanov and P. Zuman, Collection N 9, 960 (1964).Google Scholar
  4. 4.
    L. H. Chopard-Dit-Jean and E. Heilbronner, Helv. chim.,36, 144 (1953).Google Scholar
  5. 5.
    P. Zuman, Z. phys. chem. Sonderheft ctp. 243 (1958).Google Scholar
  6. 6.
    S. I. Zhdanov and L. S. Mirkin, Collection26, 370 (1960).Google Scholar
  7. 7.
    G. A. Gilbert and E. K. Rideal, Trans. Faraday Soc.,47, 396 (1951).Google Scholar
  8. 8.
    M. E. Vol'pin, Uspekhi Khimii,29, 298 (1960).Google Scholar
  9. 9.
    P. Zuman, J. Chadkowski, and F. Santavy, Collection26, 380 (1961).Google Scholar
  10. 10.
    R. W. Schmid and E. Heilbronner, Helv. chim., acta40, 950 (1957).Google Scholar
  11. 11.
    M. E. Vol'pin, S. I. Zhdanov, and D. N. Kursanov, Dokl. AN SSSR,112, 264 (1957).Google Scholar
  12. 12.
    S. I. Zhdanov and A. N. Frumkin, Dokl. AN SSSR,122, 412 (1958).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1965

Authors and Affiliations

  • A. A. Pozdeeva
    • 1
  • S. I. Zhdanov
    • 1
  1. 1.Institute of ElectrochemistryAcademy of SciencesUSSR

Personalised recommendations