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Tetracyclines

Communication 20. Configuration of 2- and 3-substituted 10-keto-9-hydroxy-1,2,3,4,4a,9,9a,10-octahydroanthracenes [1,2,3,4,4a,9a-hexahydro-10-hydroxyanthrones], and the stereochemistry of the reduction of naphthoquinone-butadiene adducts with lithium aluminum hydride
  • Yu. P. Volkov
  • M. N. Kolosov
  • V. G. Korobko
  • M. M. Shemyakin
Organic and Biological Chemistry

Summary

  1. 1.

    The configurations of some hydroanthracene compounds, synthesized as possible intermediaries in the preparation of natural 6-demethyltetracyclines and their analogs, were established.

     
  2. 2.

    The causes of the structural and steric orientation observed in the reduction of some naphthoquinone-butadiene adducts with lithium aluminum hydride were discussed.

     

Keywords

Aluminum Lithium Adduct Hydride Tetracycline 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau Enterprises Inc. 1965

Authors and Affiliations

  • Yu. P. Volkov
    • 1
  • M. N. Kolosov
    • 1
  • V. G. Korobko
    • 1
  • M. M. Shemyakin
    • 1
  1. 1.Institute for the Chemistry of Natural ProductsAcademy of SciencesUSSR

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