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Reactions of diazoacetic ester with phosphorous acid and its esters

  • B. A. Arbuzov
  • A. O. Vizel'
Brief Communications

Summary

  1. 1.

    Like diazoalkanes, diazoacetic ester reacts with phosphorous acid and with trialkyl phosphites, giving analogous products. In the reaction with triethyl phosphite the previously undescribed ethyl [(triethoxyphosphoranylidene)-azino]acetate was obtained.

     
  2. 2.

    In the reaction of diazoacetic ester with diethyl hydrogen phosphite a P-C bond is formed; this has not been observed in the case of diazoalkanes.

     

Keywords

Hydrogen Acetate Ester Ethyl Diethyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    M. I. Kabachnik and V. A. Gilyarov, Dokl. AN SSSR106, 473 (1956).Google Scholar
  2. 2.
    V. A. Gilyarov, In the Collection “Chemistry and Application of Organophosphorus Compounds,” Transactions of First Conference [in Russian], Izd. AN SSSR (1957), p. 275.Google Scholar
  3. 3.
    F. C. Palazzo and F. Maggiacomo, Gazz. chim. ital.38 [2] 115; Chem. Abstrs.2, 3038 (1908).Google Scholar
  4. 4.
    F. R. Atherton, H. T. Howard, and A. R. Todd, J. Chem. Soc. 1106 (1948).Google Scholar
  5. 5.
    M. I. Kabachnik, A. É. Shipov, and T. P. Mastryukova, Izv. AN SSSR. Otd. khim. n. 146 (1960).Google Scholar
  6. 6.
    M. I. Kabachnik and Yu. M. Polikarpov, Dokl. AN SSSR115, 512 (1957).Google Scholar
  7. 7.
    J. F. Allen and O. H. Johnson, J. Amer. Chem. Soc.77, 2871 (1955).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1964

Authors and Affiliations

  • B. A. Arbuzov
    • 1
  • A. O. Vizel'
    • 1
  1. 1.Institute of Organic ChemistryAcademy of SciencesKazan'

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