Reactions of diazoacetic ester with phosphorous acid and its esters

  • B. A. Arbuzov
  • A. O. Vizel'
Brief Communications


  1. 1.

    Like diazoalkanes, diazoacetic ester reacts with phosphorous acid and with trialkyl phosphites, giving analogous products. In the reaction with triethyl phosphite the previously undescribed ethyl [(triethoxyphosphoranylidene)-azino]acetate was obtained.

  2. 2.

    In the reaction of diazoacetic ester with diethyl hydrogen phosphite a P-C bond is formed; this has not been observed in the case of diazoalkanes.



Hydrogen Acetate Ester Ethyl Diethyl 
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Literature cited

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    V. A. Gilyarov, In the Collection “Chemistry and Application of Organophosphorus Compounds,” Transactions of First Conference [in Russian], Izd. AN SSSR (1957), p. 275.Google Scholar
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Copyright information

© Consultants Bureau Enterprises, Inc. 1964

Authors and Affiliations

  • B. A. Arbuzov
    • 1
  • A. O. Vizel'
    • 1
  1. 1.Institute of Organic ChemistryAcademy of SciencesKazan'

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