Summary
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1.
(Butylthio)borane polymer reacts with olefinic hydrocarbons, and together with the normal addition products (butyl dialkylthioborinates) trialkylboranes and bisbutylthioborane are formed as a result of symmetrization.
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2.
By the reaction of (butylthio)borane polymer with 1,5-hexadiene, 1-(butylthio)borepane is formed.
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3.
(Methylthio)borane polymer adds to olefins with formation of methyl dialkylthioborinates.
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4.
By the reaction of isoprene with (methylthio)borane polymer, 3-methyl-1-(methylthio)borolane is formed.
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Mikhailov, B.M., Shchegoleva, T.A., Sheludyakov, V.D. et al. Organoboron compounds. Russ Chem Bull 12, 579–582 (1963). https://doi.org/10.1007/BF00843945
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DOI: https://doi.org/10.1007/BF00843945