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Stereochemistry of cyclic compounds

Communication 57. Structural and steric orientation in the diene condensation of 1-vinyl-1-cyclohexene with the ethyl ψ-ester of malealdehydic acid
  • V. F. Kucherov
  • S. A. Kazaryan
  • V. M. Andreev
Organic and Biological Chemistry
  • 56 Downloads

Summary

  1. 1.

    The diene condensation of 1-vinylcyclohexene with the ethylψ -ester of malealdehydic acid was carried out: it goes structurally and sterically selectively and leads to the adduct (III) with a cis-syn configuration.

     
  2. 2.

    A study was made of the hydrolysis and isomerization of the adduct (III) and of the corresponding saturatedψ-ester (IX) into the isomericγ-aldehydic acids having a free aldehyde group at C2.

     

Keywords

Ester Hydrolysis Aldehyde Adduct Diene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    I. N. Nazarov, V. F. Kucherov, and V. M. Andreev, Izv. AN SSSR, Otd. khim. nauk, 817 (1956).Google Scholar
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    I. N. Nazarov, V. F. Kucherov, and V. M. Andreev, Izv. AN SSSR, Otd. khim. nauk, 1091 (1956).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1964

Authors and Affiliations

  • V. F. Kucherov
    • 1
  • S. A. Kazaryan
    • 1
  • V. M. Andreev
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of SciencesUSSR

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