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Hydrolysis reactions of alkylhydrocyclosilazanes and dialkylcyclosilazanes

  • D. Ya. Zhinkin
  • E. A. Semenova
  • K. A. Andrianov
Organic and Biological Chemistry
  • 49 Downloads

Summary

  1. 1.

    The stability of alkylhydtocyclosilazanes and dialkylcyclosilazanes to hydrolysis was investigated. Alkylhydrocyclosilazanes are hydrolyzed more rapidly than dialkylcyclosilazanes.

     
  2. 2.

    The hydrolytic stability of dialkylcyclosilazanes is affected by the size of the silicon-attached alkyl group. With increase in the size of this group, the rate of hydrolysis of the silazane is reduced.

     
  3. 3.

    Replacement of the hydrogen on the nitrogen of alkylhydrocyclosilazanes by a methyl group greatly reduces the rate of hydrolysis.

     

Keywords

Hydrogen Nitrogen Methyl Hydrolysis Alkyl Group 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    R. O. Sauer and R. H. Hasek, J. Am. Chem. Soc.,68, 241 (1946).Google Scholar
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    N. G. Belen'kaya, M. G. Voronkov, and B. N. Dolgov, Zh. prikl. khimii,28, 887 (1955).Google Scholar
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    K. A. Andrianov, G. Ya. Rumba, Zh. obshch. khimii,31, 4038 (1961).Google Scholar
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    R. Minne and E. G. Rochow, J. Am. Chem. Soc.,82, 5625 (1960).Google Scholar
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    N. N. Sokolov, Methods of Synthesis of Polyorganosiloxanes [in Russian] (Gosénergoizdat, 1959), p. 55.Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1964

Authors and Affiliations

  • D. Ya. Zhinkin
  • E. A. Semenova
  • K. A. Andrianov

There are no affiliations available

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