Chemistry of Heterocyclic Compounds

, Volume 19, Issue 12, pp 1267–1273 | Cite as

Reaction of 2-substituted 4,4-dimethyl-5-methylene-1,3-dioxolanes with dichlorocarbene and certain transformations of adducts obtained

  • P. I. Kazaryan
  • S. V. Avakyan
  • A. A. Gevorkyan
  • R. G. Kulinkovich
  • G. A. Panosyan
Article
  • 36 Downloads

Abstract

A series of derivatives of 4,4-dimethyl-5-methylene-1,3-dioxolane has been synthesized, and their reaction with dichlorocarbene, obtained under interphase catalysis conditions, has been studied. The adducts obtained undergo thermal isomerization into dichloroethylidene derivatives.

Keywords

Organic Chemistry Catalysis Adduct Dioxolane Catalysis Condition 

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Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • P. I. Kazaryan
    • 1
  • S. V. Avakyan
    • 1
  • A. A. Gevorkyan
    • 1
  • R. G. Kulinkovich
    • 1
  • G. A. Panosyan
    • 1
  1. 1.Institute of Organic ChemistryAcademy of Sciences of the Armenian SSRErevan

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