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Rational thermodynamics of a nonreacting binary linear fluid

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Abstract

The methods of nonlinear thermomechanics of continuous media are used for an analysis of transfer phenomena in binary fluid mixtures. From the derived relations, as a special case, are then deduced fundamental relations for the thermodynamics of irreversible processes to describe transfer phenomena in binary mixtures.

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Author information

Authors and Affiliations

  1. Institute of Chemical Technology, Prague

    I. Samohýl

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  1. I. Samohýl
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Additional information

Rational thermodynamics, in the author's view, is part of the linear thermomechanics of continuous media. This new trend in the theory of transfer phenomen is a very progressive one and represents a further development in the thermodynamics of irreversible processes. In featuring this article here, the editors wish to acquaint the readers with some interesting specific results which the author has obtained in his work on the theory of transfer in a binary mixture using the methods of continuum thermomechanics (see A. B. Lykov [32–35], Russian editor's note).

Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 25, No. 2, pp. 271–285, August, 1973. February 19, 1973.

The author thanks Academician A. V. Lykov, member of the BSSR Academy of Sciences and Prof. L. S. Kotousov for their interest in this study and for their valuable assistance in preparing the manuscript and the printed text, and also Dr. P. Vonka for his discussion.

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Samohýl, I. Rational thermodynamics of a nonreacting binary linear fluid. Journal of Engineering Physics 25, 1001–1012 (1973). https://doi.org/10.1007/BF00829851

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  • DOI: https://doi.org/10.1007/BF00829851

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