Abstract
A method of calculating the matrix of the coefficients of multicomponent diffusion in liquid mixtures on the basis of experimental data obtained by chromatographic and pulsed nuclear magnetic resonance (NMR) techniques is devised.
Similar content being viewed by others
Literature cited
A. Alimanadian and C. Colver, “A new technique for the measurement of ternary molecular diffusion coefficients in liquid systems,” Can. J. Chem. Eng.,54, No. 3, 208–213 (1976).
R. Mortimer and W. Marlow, “Experimental test of a transition state theory for diffusion coefficients in multicomponent liquids,” Ind. Eng. Chem. Fundam.,14, No. 2, 114–119 (1975).
A. A. Usmanova, A. Sh. Bikbulatov, and S. G. D'yakonov, “Measurement of diffusion coefficients of three-component liquid systems by chromatographic method,” in: Heat and Mass Transfer in Chemical Technology [in Russian], No. 5, Izd. KKhTI, Kazan (1977), pp. 65–67.
G. Taylor, “Dispersion of soluble matter in solvent flowing slowly through a tube,” Proc. R. Soc. London,219A, No. 13, 186–203 (1953).
K. Arnold and H. Toor, “Unsteady diffusion in ternary gas mixtures,” AIChE J.,13, No. 5, 909–914 (1967).
J. Huber and G. Vught, “Messund von Diffusionskoeffizienten in Gasen und Flussigkeiten nach der Arbeitsweise der chromatographie,” Ber. Bunsenges. Phys. Chem.,69, Nos. 9–10, 821–826 (1965).
K. Pratt and W. Wakeham, “The mutual diffusion coefficient of ethanol-water mixtures: determination by a rapid new method,” Proc. R. Soc. London,336A, 393–406 (1974).
A. I. Razinov, A. Kh. Abdrakhmanova, and S. G. D'yakonov, “Kinetic description of diffusion in liquid mixtures,” in: Heat and Mass Transfer in Chemical Technology [in Russian], No. 7, Izd. KKhTI, Kazan (1979), pp. 55–59.
H. Carr and E. Purcell, “Effects of diffusion on free precession in nuclear magnetic resonance experiments,” Phys. Rev.,94, No. 3, 630–638 (1954).
J. Burhard and J. Toor, “Diffusion in an ideal mixture of three completely miscible nonelectrolytic liquids — toluene, chlorobenzene, and bromobenzene,” J. Phys. Chem.,66, No. 10, 2015–2022 (1962).
F. Schuch and H. Toor, “Diffusion in the three-component liquid system methyl alcohol-n-propyl alcohol-isobutyl alcohol,” J. Phys. Chem.,67, No. 3, 540–545 (1963).
Author information
Authors and Affiliations
Additional information
Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 40, No. 1, pp. 21–27, January, 1981.
Rights and permissions
About this article
Cite this article
Usmanova, A.A., Bikbulatov, A.S., Abdrakhmanova, A.K. et al. Multicomponent diffusion in liquid mixtures by chromatographic and NMR techniques. Journal of Engineering Physics 40, 12–17 (1981). https://doi.org/10.1007/BF00825059
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00825059