Skip to main content
Log in

Coalescence of coarsely dispersed concentrated emulsions with turbulent agitation

  • Published:
Journal of engineering physics Aims and scope

Abstract

The coalescence of drops, larger than microscale vortices, induced by velocity pulsations in concentrated emulsions is examined based on the theory of locally isotropic turbulence.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Abbreviations

n:

number of drops per unit volume of emulsion

t:

time

λ0 and L:

micro- and macroscales of turbulence

ρe, ρc, and ρd :

densities of the emulsion, the continuous, and the disperse phases, respectively

σ:

interphase tension

W:

concentration of the dispersed phase

DT :

diameter of the agitating turbine

N:

rate of rotation of the turbine

D and H:

diameter and height of the mixing volume

d32 :

averaged volume-surface diameter of the drops

dm :

maximum size of drops that are stable with respect to fragmentation

f(W):

concentration dependence

¯v and ¯v(W):

averaged magnitudes of the pulsation velocity in finely dispersed and coarsely dispersed emulsions

¯gq and θ:

rates of collisions and coalescence of drops

tc and θc :

time and rate of circulation

ReM :

Reynolds number of mixer

μe :

effective viscosity of the emulsion

Kv :

constant describing the efficiency of collisions drops induced by velocity pulsations

Fv(W) and Fg(W):

functional relations between the rate of coalescence and concentration of drops in the inertial and gradient regimes

Literature cited

  1. A. N. Kolomogorov, “Fragmentation of drops in a turbulent flow,” Dokl. Akad. Nauk SSSR,66, No. 5, 825–828 (1949).

    Google Scholar 

  2. J. Hinze, “Fundamentals of hydrodynamic mechanism of splitting in dispersion process,” AIChE J.,8, No. 4, 289–295 (1962).

    Google Scholar 

  3. P. H. Calderbank, “Physical rate processes in industrial fermentation. Part I. The interfacial area in gas-liquid contacting with mechanical agitation,” Trans. Inst. Chem. Eng.,36, 443–459 (1958).

    Google Scholar 

  4. D. Brown and K. Pitt, “Drop size distribution of stirred noncoalescing liquid-liquid systems,” Chem. Eng. Sci.,27, 577–583 (1972).

    Google Scholar 

  5. J. Mlynek and W. Resnik, “Drop size in an agitated liquid-liquid system,” AIChE J.,18, No. 1, 122–127 (1972).

    Google Scholar 

  6. C. A. Coulaglou and L, L. Tavlarides, “Drop size distributions and coalecence frequencies of liquid-liquid dispersions in flow vessels,” AIChE J., _22, No. 2, 289–297 (1976).

    Google Scholar 

  7. S. Gnanasundaram, T. E. Degaleeson, and G. S. Laddha, “Prediction of mean drop size in bath agitated vessels,” Can. J. Chem. Eng.,57, No. 2, 141–144 (1979).

    Google Scholar 

  8. H. Chen and S. Middleman, “Drop size distribution in agitated liquid-liquid systems,” AIChE J.,13, No. 5, 989–995 (1967).

    Google Scholar 

  9. M. A. Delichatsios and R. F. Probstein, “The effect of coalescence on the average drop size in liquid-liquid dispersions,” Ind. Eng. Chem., Fund.,15, No. 2, 137–138 (1976).

    Google Scholar 

  10. T. Mišek, “Coalescence of drops in an agitated liquid-liquid extractor,” Collect. Czech. Chem. Commun.,29, No. 9, 2086–2093 (1964).

    Google Scholar 

  11. M. Doulach, “An effect of hold-up on drop sizes in liquid-liquid dispersions,” Ind. Eng. Chem., Fund.,14, No. 2, 137–138 (1975).

    Google Scholar 

  12. D. Holmes, R. Vonchen, and J. Decker, “Fluid flow in turbulent baffled tanks. I. Circulation time,” Chem. Eng. Sci.,19, No. 3, 201–208 (1964).

    Google Scholar 

  13. A. K. Rozentsvaig and L. P. Pergushev, “Coalescence of concentrated finely dispersed emulsions with turbulent agitation,” Inzh.-Fiz., Zh.,40, No. 6, 1013–1018 (1981).

    Google Scholar 

  14. J. G. Perry, Chemical Engineering Handbook [Russian translation], Vol. 2, Khimiya, Leningrad (1969).

    Google Scholar 

  15. H. Schwartzberg and R. Treybal, “Fluid particles motion in turbulent stirred tanks,” Ind. Eng. Chem., Fund.,7, 1–2 (1968).

    Google Scholar 

  16. V. G. Levich, Physicochemical Hydrodynamics, Prentice-Hall (1962).

  17. W. J. Howarth, “Measurement of coalescence frequency in an agitated tank,” AIChE J.,13, No. 5, 1007–1013 (1967).

    Google Scholar 

  18. R. Kuboi, J. Komasawa, and T. Otake, “Collision and coalescence of dispersed drops in turbulent liquid flow,” J. Chem. Eng. Jpn.,5, No. 4, 423–424 (1972).

    Google Scholar 

  19. K. Shiloch, S. Sideman, and W. Resnik, “Coalescence and breakup in dilute polydispersions,” Can. J. Chem. Eng.,51, No. 5, 542–549 (1973).

    Google Scholar 

  20. L. P. Pergushev and A. L. Rozentsveig, “Effect of inhomogeneity of the dispersed phase on coalescence processes and mass exchange in liquid emulsions,” Zh. Prikl. Mekh. Tekh. Fiz., No. 4, 74–81 (1980).

    Google Scholar 

  21. R. Shinnar, “On the behavior of liquid dispersion in mixing vessels,” J. Fluid Mech.,10, No. 2, 259–275 (1961).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 42, No. 1, pp. 27–33, January, 1982.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rozentsvaig, A.K. Coalescence of coarsely dispersed concentrated emulsions with turbulent agitation. Journal of Engineering Physics 42, 19–24 (1982). https://doi.org/10.1007/BF00824984

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00824984

Keywords

Navigation