Skip to main content
SpringerLink
Log in

On the catalytic effect of thiolactams on the electrochemical reduction of Zn(II) ions

Zum katalytischen Effekt von Thiolactamen auf die elektrochemische Reduktion von Zn(II)-Ionen

  • Anorganische Und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

The electroeduction of Zn(II) ions in 1M NaClO4 in the presence of thiolactams has been studied by means of the faradaic impedance method in wide frequency ranges. The standard rate constants are found to be a linear function of the surface excesses of thiolactams. Catalytic activity of thiolactams increases in the following order: thiopyrrolidone, thiopiperidinone, thiocaprolactam; the enthalpies of activation decrease in this order. The differences in the catalytic activity of thiolactams result mainly from the double layer effect.

Zusammenfassung

Die Elektroeduktion von Zn(II)-Ionen in 1M NaClO4 in Gegenwart von Thiolactamen wurde mittels derFaradayschen Impedanzmethode über große Frequenzbereiche untersucht. Die Standardgeschwindigkeitskonstanten sind eine lineare Funktion der Überschußoberfläche der Thiolactame. Deren katalytische Aktivität steigt in der Reihenfolge Thiopyrrolidon — Thiopiperidinon — Thiocaprolactam; die Aktivierungsenthalpien sinken in der angegebenen Reihenfolge. Die Unterschiede in der katalytischen Aktivität der Thiolactame sind hauptsächlich auf den Doppelschichteffekt zurückzuführen.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Hush NS, Blackledge J (1963) J Electroanal Chem5: 420

    Google Scholar 

  2. Salie G (1970) Phys Chem Leipz244: 1

    Google Scholar 

  3. Loves VV (1972) In: Conway BE, Bockris J O'M (eds) Modern aspects of electrochemistry, vol 7. Butterworths, London

    Google Scholar 

  4. Hurlen T, Eriksrud E (1973) J Electroanal Chem45: 405

    Google Scholar 

  5. Van der Pol F, Sluyters-Rehbach M, Sluyters JH (1975) J Electroanal Chem58: 177

    Google Scholar 

  6. Andreu R, Sluyters-Rehbach M, Remijnse AG, Sluyters JH (1982) J Electroanal Chem134: 101

    Google Scholar 

  7. Tanaka N, Tamamushi T (1964) Electrochim Acta9: 963

    Google Scholar 

  8. Blackledge J, Hush NS (1963) J Electroanal Chem5: 435

    Google Scholar 

  9. Tamamushi R, Ishibashi R, Tanaka N (1962) Z Phys Chem NF35: 205

    Google Scholar 

  10. Teppema J, Sluyters-Rehbach M, Sluyters JH (1968) J Electroanal Chem16: 165

    Google Scholar 

  11. Andreu R, Sluyters-Rehbach M, Sluyters JH (1984) J Electroanal Chem171: 139

    Google Scholar 

  12. Sykut K, Dalmata G, Nowicka B, Saba J (1978) J Electroanal Chem90: 299

    Google Scholar 

  13. Sykut K, Saba J, Marczewska B, Dalmata G (1984) J Electroanal Chem178: 295

    Google Scholar 

  14. Dalmata G, Saba J, Marczewska B, Sykut K (1986) Ann UMCS41: 81

    Google Scholar 

  15. Sikorska-Tomicka H (1967) Chem Anal12: 1291

    Google Scholar 

  16. Sikorska-Tomicka H (1968) Mikrochim Acta 1106

  17. Sikorska-Tomicka H (1985) Chem Anal30: 657

    Google Scholar 

  18. Madan SK (1967) J Inorg Nucl Chem29: 2765

    Google Scholar 

  19. Sikorska-Tomicka H (1971) Microchem J16: 437

    Google Scholar 

  20. Wirth NV (1953) Pat USA 2, 688, 014

  21. Turnham DS (1965) J Electroanal Chem10: 19

    Google Scholar 

  22. Furman NS, Cooper W Ch (1950) J Am Chem Soc72: 5667

    Google Scholar 

  23. Ravdel AA, Moskievich AS (1971) Zh Prikl Khim44: 1781

    Google Scholar 

  24. Galus Z (1979) Elektroanalityczne metody wynaczania stałych fizykochemicznych. PWN Warszawa

    Google Scholar 

  25. Sluyters JH, Oomen JJC (1960) Rec Trav Chim Pays-Bas79: 1101

    Google Scholar 

  26. Sluyters JH (1960) Rec Trav Chim Pays-Bas79: 1092

    Google Scholar 

  27. Sluyters-Rehbach M, Sluyters JH (1970) In: Bard AJ (ed) Electroanalytical chemistry, vol 4. Dekker, New York

    Google Scholar 

  28. Frumkin AN (1961) In: Delahay P (eds) Advances in electrochemistry and electrochemical engineering, vol 3. Interscience, New York

    Google Scholar 

  29. Delahay P (1965) Double layer and electrode kinetics. Interscience, New York

    Google Scholar 

  30. Temkin MJ (1948) Zh Fiz Khim22: 1081

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, M. Curie-Skłodowska University, PL-20031, Lublin, Poland

    G. Dalmata

Authors
  1. G. Dalmata
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dalmata, G. On the catalytic effect of thiolactams on the electrochemical reduction of Zn(II) ions. Monatsh Chem 126, 1195–1201 (1995). https://doi.org/10.1007/BF00824297

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00824297

Keywords

Search

Navigation