Abstract
A simple kinetic model shows that a radical-chain mechanism can account for the high activity and selectivity found for oxidation of isobutane tot-butanol catalyzed by highly halogenated metalloporphyrins.
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Labinger, J.A. A simplified model for catalyzed isobutane autoxidation: implications for the mechanism of catalysis by halogenated porphyrin complexes. Catal Lett 26, 95–99 (1994). https://doi.org/10.1007/BF00824035
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DOI: https://doi.org/10.1007/BF00824035