Conclusions
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1.
The probability of recombination radiation enables us to determine the correlation between the principal phosphorescence parameter γ and the degree of excitation z, so that the problem is reduced to finding either of these. This makes the correlation method convenient for experimental work.
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2.
The correlation method enables investigation of the temperature dependence of the parameters,
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3.
The principal parameter is determined without relevence to the thermal characteristics ɛ and p0, which in turn enables us to determine the latter; this removes the limitations imposed on the principal parameter. The correlation method can thus be used to determine the thermal characteristics in the kinetics of electronic processes.
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4.
The very important parameters η, no, and ν remain undetermined. They cannot be evaluated, since the differential and integral forms are linear and homogeneous in (1 − γ), γυη, and p (this is why γ is determined by the correlation method). The physical reason for this is nonradiative transition
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References
E. I. Adirovich, Some Problems in the Theory of Luminescence by Crystals [in Russian], GITTL, 1951.
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Arutyunyan, R.K. Determining the parameters of crystal phosphors. Soviet Physics Journal 8, 31–35 (1965). https://doi.org/10.1007/BF00823733
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DOI: https://doi.org/10.1007/BF00823733