Abstract
Intermolecular spectra are reported for acetonitrile and benzonitrile between −196 °C and 100–140 °C. Structural changes can be established from the integral intensity, peak frequencies, and effective molecular vibration frequencies. There is a polymorphic transition in crystalline acetonitrile between −50 and −60 °C, while there is a change in the structure of liquid benzonitrile in the range 0–10 °C. There are peaks in the intermolecular spectrum of benzonitrile in the liquid state.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
A. V. Sechkarev and P. T. Nikolaenko, Izv. VUZ, Fizika, No. 4, 104 (1969).
P. T. Nikolaenko and A. A. Artamonov, Izv. VUZ, Fizika, No. 2, 153 (1969).
A. V. Sechkarev, A. A. Artamonov, B. P. Nevzorov, P. T. Nikolaenko, and N. M. Protasov, Izv. VUZ, Fizika, No. 5, 7 (1970).
B. P. Nevzorov and A. V. Sechkarev, Izv. VUZ, Fizika, No. 2, 75 (1971).
P. T. Nikolaenko, A. V. Sechkarev, N. M. Protasov, and N. G. Torgunakov, Proceedings of the Sixth Siberian Spectroscopy Conference [in Russian], Tomsk (1968).
P. A. Casabella and P. J. Bray, J. Chem. Phys.,29, 1105 (1958).
H. Negita, P. A. Casabella, and P. J. Bray, J. Chem. Phys.,32, 314 (1960).
E. L. Pace and Lewis J. Noe, J. Chem. Phys.,15, 5317 (1968).
G. I. Baranov and A. V. Sechkarev, Izv. VUZ, Fizika, No. 3, 51 (1968).
I. I. Sobel'man, Izv. Akad. Nauk SSSR, Ser. Fiz.,17, 554 (1953).
A. A. Artamonov and A. V. Sechkarev, Izv. VUZ, Flzika, No. 7, 77 (1968).
N. I. Dvorovenko and A. V. Sechkarev, Izv. VUZ, Fizika, No. 4, 6 (1964).
P. T. Nikolaenko, in: Papers on Physics. Problems of Spectroscopy [in Russian], Kemerova (1967), p. 58.
B. M. Bishui, Indian J. Phys.,22, 167 (1948).
D. E. Milligan and M. E. Jacok, J. Molec. Spectrosc.,8, 126 (1962).
E. F. Gross and M. F. Vuks, J. de Phys.,6, 457 (1935).
A. V. Sechkarev and P. T. Nikolaenko, Dokl. Akad. Nauk SSSR,182, No. 1, 84 (1968).
S. Kastha, Ind. J. Phys.,32, 437 (1958).
M. Suzuki, T. Yokogama, and M. Ito, Spectrochim. Acta,24a, 1091 (1968).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 92–95, August, 1971.
Rights and permissions
About this article
Cite this article
Torgunakov, N.G., Nikolaenko, P.T. & Sechkarev, A.V. Vibrational spectroscopy and the intermolecular dynamics of condensed states V. Temperature dependence of intermolecular spectra of acetonitrile and benzonitrile. Soviet Physics Journal 14, 1093–1096 (1971). https://doi.org/10.1007/BF00820074
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00820074