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Soviet Physics Journal

, Volume 10, Issue 7, pp 46–49 | Cite as

The generation of cationic vacancies in the electrolysis of doped alkali halide crystals

  • Ya. N. Pershits
  • E. V. Pavlov
Article

Abstract

The introduction of metallic cadmium impurity into the melt reduces the electrical conductivity of KCl and KBr in the structure-sensitive range by 2–3 orders of magnitude. The electrolytic introduction of gold and nickel ions restores the impurity conductivity as a result of interaction of gold and nickel ions with the cadmium. The migration energies of cationic vacancies in KCl and KBr were found to be 0.67 eV and 0.62 eV, respectively.

Keywords

Gold Nickel Migration Cadmium Electrical Conductivity 
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References

  1. 1.
    H. Gründig, Zs. f. Phys.,158, 577, 1960.Google Scholar
  2. 2.
    H. Kanzaki, K. Kido, and T. Ninomiya, J. Appl. Phys.,33, no. 1, 482, 1962.Google Scholar
  3. 3.
    T. Miyata, R. Sano, and T. Tomiki, J. Phys. Soc. Japan, 20, no. 4, 638, 1965.Google Scholar
  4. 4.
    H. Gründig, Zs. Phys.,182, no. 5, 477, 1965.Google Scholar
  5. 5.
    L. M. Shamovskii, A. A. Dunina, and M. I. Gosteva, DAN SSSR,111, no. 4, 811, 1956.Google Scholar
  6. 6.
    Ya. N. Pershits, Uch. zapiski Pskovskogo ped. in-ta,16, 9, 1963.Google Scholar
  7. 7.
    H. Keltingand, H. Witt, Zs. Phys.,126, 697, 1949.Google Scholar
  8. 8.
    Ya. N. Pershits, Izv. VUZ. Fizika, no. 2, 131, 1964.Google Scholar
  9. 9.
    Ya. N. Pershits, Izv. VUZ. Fizika, no. 3, 3, 1962.Google Scholar
  10. 10.
    F. Koch and C. Wagner, Zs. Phys. Chem. (B)38, 295, 1937.Google Scholar
  11. 11.
    L. M. Shamovskii, L. M. Rodionova, M. V. Pashkovskii, N. A. Tsal and N. D. Nabitovich, collection: Proceedings of the Fourth Conference on Scintillators [in Russian], 1965.Google Scholar
  12. 12.
    A. Liddiard, Ionic Conductivity of Crystals [Russian translation], IIL, Moscow, 1962.Google Scholar

Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • Ya. N. Pershits
    • 1
  • E. V. Pavlov
    • 1
  1. 1.Pskov State Pedagogical InstituteUSSR

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