Abstract
The line intensities in the H2O band are found in first-order perturbation theory with an account of the nonrigidity of the molecule, the Δk effect, and the Coriolis interaction. The equations found contain three parameters, which are determined from the experimental line intensities. The relationship between these results and previous results is discussed.
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I. I. Ippolitov and Yu. S. Makushkin, Opt. Spektrosk.,24, 531 (1968).
V. E. Zuev, I. I. Ippolitov, Yu. S. Makushkin, A. A. Orlov, and V. V. Fomin, Opt. Spektrosk.,25, 36 (1968).
D. M. Gates, R. F. Calfee, D. W. Hansen, and W. S. Benedict, “Line parameters and computed spectra for water vapor bands at 2.7 μ, ” NBS Monograph, 71, Washington (August, 1964).
W. S. Benedict and R. F. Calfee, “Line parameters for the 1.9 and 6.3 μ water vapor bands,” ESSA Professional Paper 2, 1967.
M. T. Emerson and D. F. Eggers, J. Chem. Phys.,37, 251 (1962).
M. A. El'yashevich, Trudy GOI,12, No. 6 (1944).
P. Gross, R. Hainer, and G. King, J. Chem. Phys.,12, No. 106 (1938).
D. K. Prinz, Appl. Optics,7, 689 (1968).
W. S. Benedict and L. D. Caplan, J. Quant. Spectrosc. Radiative Transfer,4, 453 (1964).
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Translated from Izvestiya, VUZ. Fizika, No. 3, pp. 101–107, March, 1970.
The authors thank professor V. E. Zuev for constant support during this study, and G. R. Kontarev and V. P. Sadokhina for writing the programs and carrying out the calculations.
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Ippolitov, I.I., Makushkin, Y.S. Effect of vibration-rotation interactions on the line intensity in the H2O 6.3 μ, band. Soviet Physics Journal 13, 357–361 (1970). https://doi.org/10.1007/BF00818326
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DOI: https://doi.org/10.1007/BF00818326