Skip to main content
SpringerLink
Log in

Silica anchored bis(trialkylphosphine) platinum oxalate. A photogenerated catalyst for olefin hydrosilation

Siliziumverankerte Bis(trialkylphosphin)platinoxalate. Ein photogenerierter Katalysator für die Hydrosilierung von Olefinen (Kurze Mitteilung)

Short communication

  • Anorganische Und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Ultraviolet irradiation of the silica attached complex Pt(C2O4)L 2, [L=(H3CO)3Si(CH2)2PEt 2], yields a [SiO2]-L 2Pt species that catalyzes olefin hydrosilation or adds 2 CO to yield a surface dicarbonyl complex.

Zusammenfassung

Die Ultraviolettbetrahlung des siliziumverknüpften Komplexes Pt(C2O4)L 2 [L=(H3CO)3Si(CH2)2PEt 2] ergab eine [SiO2]-L 2Pt-Spezies, die die Hydrosilierung von Olefinen katalysiert oder unter Bildung eines Oberflächen-Dicarbonylkomplexes 2 CO addiert.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Bailey D. C., Langer S. H., Chem. Rev.81, 109 (1981).

    Google Scholar 

  2. Neibergall V. H., Makromol. Chem.52, 218 (1962).

    Google Scholar 

  3. Paonessa R. S., Prignano A. L., Trogler W. C., Organometallics4, 647 (1985).

    Google Scholar 

  4. Chini P.,Longini G., J. Chem. Soc. (A)1970, 1542.

  5. Chatt J.,Chini P., J. Chem. Soc. (A)1970, 1538.

  6. Harrod J. F., Chalk A. J., Organic Synthesis via Metal Carbonyls (Wender I., Pino P., eds.), Vol. 2, 673. New York: Wiley-Interscience. 1977;

    Google Scholar 

  7. Speier J. L., Adv. Organomet. Chem.17, 407 (1979).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, D-006, University of California at San Diego, 92093, La Jolla, California, USA

    Andrea L. Prignano & William C. Trogler

Authors
  1. Andrea L. Prignano
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. William C. Trogler
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Dedicated to Prof. Dr.Kurt L. Komarek on the occasion of his 60th birthday.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Prignano, A.L., Trogler, W.C. Silica anchored bis(trialkylphosphine) platinum oxalate. A photogenerated catalyst for olefin hydrosilation. Monatsh Chem 117, 617–619 (1986). https://doi.org/10.1007/BF00817899

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00817899

Keywords

Search

Navigation