Summary
The title compound was prepared from (−)(S) p -2,7-dibromo-1,6-methano[10]annulene by treatment withn-Bu-Li and subsequent quenching with D2O. The optical rotations at four wavelengths and the circular dichroism spectrum are reported.
Zusammenfassung
Die Titelverbindung wurde aus (−)(S) p -2,7-Dibrom-1,6-methano[10]annulen durch Umsetzung mitn-Bu-Li und nachfolgende Reaktion mit D2O dargestellt. Optische Rotationen bei vier Wellenlängen und das Circulardichroismus-Spektrum wurden bestimmt.
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References and footnotes
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Meyer, A., Schlögl, K. Chirality due to deuterium substitution: synthesis and circular dichroism of (+)(R) p -2,7-dideuterio-1,6-methano[10]annulene. Monatsh Chem 123, 465–467 (1992). https://doi.org/10.1007/BF00817603
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DOI: https://doi.org/10.1007/BF00817603