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Synthesis and properties of an ω,ω′-appended eighteen carbon chains hypericin derivative

Synthese und Eigenschaften eines mit C18-Ketten ω,ω′-substituierten Hypericinderivats

  • Organische Chemie Und Biochemie
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Summary

An ω,ω′-appended eighteen carbon chains hypercin derivative (2) was synthesized starting from emodin. The overall yield of the seven step synthesis was 12%. The1H and13C NMR, absorption, and emission spectroscopic properties were measured;2 can be dissolved even in apolar solvents and polyethylene.

Zusammenfassung

Ein in den Positionen ω,ω′ mit zwei C18-Ketten substituiertes Derivat des Hypericins (2) wurde ausgehend von Emodin synthetisiert. Die Gesamtausbeute der siebenstufigen Synthese betrug 12%. Die1H- und13C-NMR, absorptions- und emissionsspektroskopischen Eigenschaften wurden gemessen;2 kann sogar in apolaren Lösungsmitteln und Polyethylen gelöst werden.

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Authors and Affiliations

  1. Institut für Chemie, Johannes Kepler Universität Linz, A-4040, Linz, Austria

    H. Falk & T. N. H. Tran

Authors
  1. H. Falk
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  2. T. N. H. Tran
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Falk, H., Tran, T.N.H. Synthesis and properties of an ω,ω′-appended eighteen carbon chains hypericin derivative. Monatsh Chem 127, 717–723 (1996). https://doi.org/10.1007/BF00817262

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  • DOI: https://doi.org/10.1007/BF00817262

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