Abstract
The formation of chlorocomplexes of cobalt(II) chloride in propylene carbonate (PC) solution has been investigated spectrophotometrically and conductometrically. The influence of the nature of the solvent on the coordination state of cobalt(II) chloride is discussed in terms of donor number (DN) and dielectric constant.
Zusammenfassung
Die Bildung von Chlorokomplexen des Kobalt(II)-chlorids in Propandiol-1,2-carbonat (PC) wird auf spektrophotometrischem und konduktometrischem Wege untersucht. Die Abhängigkeit des Koordinationsverhaltens von Kobalt(II)-chlorid von der Donorzahl (DZ) und der Dielektrizitätskonstante in verschiedenen Lösungsmitteln wird diskutiert.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Libuś W, Uruska I (1966) Inorg Chem 5: 256
Libuś W, Grzybkowski W, Walczak M (1970) Bull Ac Pol Chim 18: 141
Kamieńska E, Uruska I (1976) Bull Ac Pol Chim 24: 567
Pilarczyk M, Klinszporn L (1985) Bull Ac Pol Chim 33: 68
Grzybkowski W, Pilarczyk M (1986) J Chem Soc Faraday Trans I 82: 1703
Libuś W, Pilarczyk M, Pastewski R, Szuchnicka T (1982) Electrochim Acta 27: 573
Libuś W, Grzybkowski W (1978) Electrochim Acta 23: 791
Pilarczyk M Bull Ac Pol Chim (in press)
Gutmann V (1972) Top Curr Chem 27: 59
Ahrland S, Bjork N (1975) Coord Chem Rev 16: 115
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Pilarczyk, M. The coordination state of CoCl2 in propylene carbonate. Monatsh Chem 118, 1225–1235 (1987). https://doi.org/10.1007/BF00816865
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00816865