Skip to main content
SpringerLink
Log in

Solvent effects and correlation with Reichardt'sE T values on charge transfer spectra of bis(2,2′-bipyridyl)biscyanoiron(II)

Lösungsmitteleffekte der Charge-Transfer-Spektren von Bis(2,2′-bipyridyl)biscyanoeisen(II) und Korrelation mit denE T -Werten nach Reichardt

  • Organische Chemie Und Biochemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The solvatochromic behaviour of biscyano-bis(2,2′-bipyridyl)iron(II) in a variety of solvents is described. The frequencies are correlated with Reichardt's solvent parameterE T . Various trends are indicated, solvatochromic shifts of the title complex in various aqueous mixtures ofDMF and 2-butoxy ethanol are also reported.

Zusammenfassung

Es wird das solvatochrome Verhalten von Bis(2,2′-bipyridyl)biscyanoeisen(II) in einer Reihe von Lösungsmitteln beschrieben. Die Frequenzen der Absorption werden nach derE T -Lösungsmittelskala von Reichardt korreliert. Dabei zeigen sich verschiedene Gesetzmäßigkeiten. Es wurden auch die solvatochromen Verschiebungen in Mischungen vonDMF und 2-Butoxyethanol untersucht.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Blandamer M. J., Burgess J. (1988) Transition Met. Chem.13: 1

    Google Scholar 

  2. Burgess J., Shraydeh B. (1992) Polyhedr.11: 2015

    Google Scholar 

  3. Burgess J., Radulovic S., Sanchez F. (1987) Transition Met. Chem.12: 529

    Google Scholar 

  4. Bin Ali R., Banerjee P., Burgess J., Smith A. E. (1988) Transition Met. Chem.13: 107

    Google Scholar 

  5. Al-Alousy A., Burgess J. (1990) Inorg. Chim. Acta169: 167

    Google Scholar 

  6. Shilt A. A. (1960) J. Am. Chem. Soc.82: 3000

    Google Scholar 

  7. Gutmann V. (1988) Monatsh. Chem.119: 1251;

    Google Scholar 

  8. Mayer U., Gutmann V., Gerger W. (1975) Monatsh. Chem.106: 1235

    Google Scholar 

  9. Laurence C., Nicolet P., Reichardt C. (1987) Bull. Soc. Chim. Fr.: 125

  10. Burgess J. (1970) Spectro. Chim. Acta26A: 1369, 1957

    Google Scholar 

  11. Barbieri A. G. (1934) Atti Accad. NazL. Lincei20: 273

    Google Scholar 

  12. Schilt A. A., Sutherland J. W. (1964) Anal. Chem.36: 1805

    Google Scholar 

  13. Bjerrum J, Adamson A. W., Bostrup O. (1956) Acta Chem. Scand.10: 329

    Google Scholar 

  14. Adams D. M. (1969) J. Chem. Soc.A: 87

    Google Scholar 

  15. Maddock A. G. (1986) J. Chem. Soc. Dalton. Trans.11: 2349

    Google Scholar 

  16. Burgess J., Drasdo D. N., Shraydeh B. (1992) J. Chem. Res. (S)8: 288

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, Faculty of Science, An-Najah National University Nablus, West Bank, via Israel

    Bassem Farah Shraydeh

  2. Department of Chemistry, University of Leicester, LE1 7RH, Leicester, United Kingdom

    John Burgess

Authors
  1. Bassem Farah Shraydeh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. John Burgess
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shraydeh, B.F., Burgess, J. Solvent effects and correlation with Reichardt'sE T values on charge transfer spectra of bis(2,2′-bipyridyl)biscyanoiron(II). Monatsh Chem 124, 877–880 (1993). https://doi.org/10.1007/BF00816410

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00816410

Keywords

Search

Navigation