Conclusions
An EPR spectrum which may be assigned to the V4+ ion has been observed in vanadium-tellurite glasses. Tetravalent vanadium enters the tellurium-oxygen framework in the form of octahedral [(V4+O)O5] complexes.
Literature cited
V. A. Tolkachev and A. I. Mikhailov, Pribory i Tekh. Éksperim., No. 6, (1964).
V. Tore and R. Aasa, Paramagnetic Resonance, Vol. 2, Academic Press, New York-London (1963), pp. 509–519.
N. S. Garif'yanov and N. F. Usacheva, Zh. Fiz. Khim.,38, 1367 (1964).
C. J. Ballhausen, Introduction to Ligand Field Theory, McGraw-Hill, New York (1962).
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, Vol. 12, No. 7, pp. 143–144, July, 1969.
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Zamotrinskaya, E.A., Kulemin, N.P. EPR of vanadium in vanadium-tellurite glasses. Soviet Physics Journal 12, 954–955 (1969). https://doi.org/10.1007/BF00815884
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DOI: https://doi.org/10.1007/BF00815884