Catalysis Letters

, Volume 40, Issue 3–4, pp 203–206 | Cite as

Probing the bimetallic RhCo3 cluster preserved on SiO2 after thermal treatment under O2 by hydroformylation

  • Lin Huang
  • Yide Xu
Article

Abstract

RhCo3(CO)12/SiO2, after decarbonylation under atmospheric O2 at 623 K, exhibits excellent catalytic performances in atmospheric ethylene hydroformylation at 423 K, which is consistent with the corresponding catalysis by the bimetallic cluster catalyst RhCo3/SiO2.

Keywords

silica-supported RhCo3(CO)12 oxygen treatment hydroformylation 

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Copyright information

© J.C. Baltzer AG, Science Publishers 1996

Authors and Affiliations

  • Lin Huang
    • 1
  • Yide Xu
    • 1
  1. 1.State Key Laboratory of Catalysis, Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalianPeople's Republic of China

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