Advertisement

Catalysis Letters

, Volume 40, Issue 3–4, pp 163–166 | Cite as

Highly active polymer-alumina dually supported palladium catalysts for the carbonylation of allyl halides under atmospheric pressure

  • Hanrong Gao
  • Yun Xu
  • Shijian Liao
  • Jing Liu
  • Han Hong
Article
  • 37 Downloads

Abstract

Polymer-alumina dually supported palladium catalysts (PVP-Pd/Al2O3, PVP = poly(N-vinyl-2-pyrrolidone); PPPO-Pd/ Al2O3, PPPO = phosphinated poly(phenylene oxide)) were used to catalyze the carbonylation of allyl halides to form butenoic acid under the mild conditions of 40‡C and 0.1 MPa. These catalysts exhibit high activity and stability towards the carbonylation of allyl halides. The maximum turnovers (mol CO/mol Pd) of PPPO-Pd/Al2O3 are up to 8.2×105 and 4.6×105 for the carbonylation of allyl bromide and allyl chloride respectively in an aqueous NaOH/benzene medium.

Keywords

alumina supported palladium catalysts carbonylation allyl halides 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. [1]
    G.P. Chiusoli, Chim. Ind. 41 (1959) 503.Google Scholar
  2. [2]
    F. Joó and H. Alper, Organometallics 4 (1985) 1775.Google Scholar
  3. [3]
    J. Tsuji, M. Morikawa and J. Kiji, Tetrahedron Lett. (1963) 1811.Google Scholar
  4. [4]
    R.F. Heck,Palladium Reagents in Organic Synthesis (Academic Press, London, 1985).Google Scholar
  5. [5]
    D. Milstein, Organometallics 1 (1982) 888.Google Scholar
  6. [6]
    J. Kiji, T. Okano, W. Nishiumi and H. Konishi, Chem. Lett. (1988) 957.Google Scholar
  7. [7]
    T. Okano, N. Okabe and J. Kiji, Bull. Chem. Soc. Jpn. 65 (1992) 2589.Google Scholar
  8. [8]
    E. Bayer and W. Schumann, J. Chem. Soc. Chem. Commun. (1986) 949.Google Scholar
  9. [9]
    F. Joó, S. Benkó, I. Horváth, Z. Török L. Nádasdi and L. Vigh, React. Kinet. Catal. Lett. 48 (1992) 619.Google Scholar
  10. [10]
    H. Gao, Y. Xu, S. Liao and D. Yu, Chinese Chem. Lett. 3 (1989) 351.Google Scholar
  11. [11]
    H. Gao, Y. Xu, S. Liao and D. Yu, React. Polym. 23 (1994) 113.Google Scholar
  12. [12]
    M.D. Fryzuk and B. Bosnich, J. Am. Chem. Soc. 99 (1977) 6262.Google Scholar
  13. [13]
    B.J. Story and W.J. Koros, J. Membrane Sci. 67 (1992) 191.Google Scholar
  14. [14]
    H. Alper, Fund. Res. Homogeneous Catal. 4 (1984) 79.Google Scholar
  15. [15]
    J. Liu, Y. Xu, S. Liao, C. Li and Q. Xin, Chinese J. Mol. Catal. 6 (1993) 32.Google Scholar
  16. [16]
    J. Liu, Y. Xu, S. Liao, C. Li and Q. Xin, Chinese J. Catal. 14 (1993) 73.Google Scholar

Copyright information

© J.C. Baltzer AG, Science Publishers 1996

Authors and Affiliations

  • Hanrong Gao
    • 1
  • Yun Xu
    • 1
  • Shijian Liao
    • 1
  • Jing Liu
    • 1
  • Han Hong
    • 1
  1. 1.Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalianPeople's Republic of China

Personalised recommendations